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Preparation, Structure and Reactivity of Et2N(Me3Si)2SiK

✍ Scribed by Michaela Zirngast; Judith Baumgartner; Christoph Marschner

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
408 KB
Volume
2008
Category
Article
ISSN
1434-1948

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On the Staudinger Reaction of SP(N3)3 wi
On the Staudinger Reaction of SP(N3)3 with PPh3 and(Me3Si)2N–(Me3Si)N–PPh2
✍ Nadine GΓΆtz; Sebastian Herler; Peter Mayer; Axel Schulz; Alexander Villinger; Ja πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 187 KB

## Abstract The Staudinger reactions of SP(N~3~)~3~ (1) with 1, 2 and 3 equiv. of triphenylphosphane PPh~3~ and (TMS)~2~N–(TMS)N–PPh~2~ (2) have been investigated (TMS = Me~3~Si). Reaction with PPh~3~ yields the single and double Staudinger products SP(N~3~)~2~NPPh~3~ (3) and SP(N~3~)(NPPh~3~)~2~ (