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Reactivity of the CF 3 CFHO Radical: Thermal Decomposition and Reaction with O 2†

✍ Scribed by Wu, Fuxiang; Carr, Robert W.

Book ID
127244592
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
137 KB
Volume
107
Category
Article
ISSN
1089-5639

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A kinetic study of the CF3CFHO2 + NO rea
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The kinetics of the reaction of CF,CFHO, radicals with NO was studied by flash photolysis-time-resolved mass spectrometry. From the kinetic growth rate of NO: molecular ions the rate coefficient of the reaction CF,CFHO, + NO -+ CF,CFHO + NO, was determined to be k = (1.31 &-0.30) X 10-l' cm3 molecul

Absolute rate constants for the self rea
Absolute rate constants for the self reactions of HO2, CF3CFHO2, and CF3O2 radicals and the cross reactions of HO2 with FO2, HO2 with CF3CFHO2, and HO2 with CF3O2 at 295 K
✍ Jens Sehested; Trine Møgelberg; Kjell Fagerström; Gharib Mahmoud; Timothy J. Wal 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 175 KB 👁 2 views

The kinetics of the self-reactions of HO 2 , CF 3 CFHO 2 , and CF 3 O 2 radicals and the cross reactions of HO 2 with FO 2 , HO 2 with CF 3 CFHO 2 , and HO 2 with CF 3 O 2 radicals, were studied by pulse radiolysis combined with time resolved UV absorption spectroscopy at 295 K. The rate constants f