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CF3CFHO• radical: Decomposition vs. reaction with O2

✍ Scribed by W. F. Schneider; T. J. Wallington; J.R. Barker; E. A. Stahlberg

Book ID: 112009043
Publisher: Wiley (John Wiley & Sons)
Year: 1998
Tongue: English
Weight: 694 KB
Volume: 102
Category: Article
ISSN: 0372-8323
DOI: 10.1002/bbpc.19981021215

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The reaction of CF3 radicals with Ha0 (D20) has been studied over the range of 533-723 K using the photolysis and the pyrolysis of CFJ as the free radical source. Arrhenius pa- rameters for the reactions where X = H or D, relative to CF:j radical recombination are given by log kHlkf'2 = (5.12 f 0.1