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Reactivity of Paramagnetic FeII–Bis(amidinate) Complexes

✍ Scribed by Erica Jellema; Timo J. J. Sciarone; Noa M. Navarrete; Marten J. Hettinga; Auke Meetsma; Bart Hessen

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
713 KB
Volume
2011
Category
Article
ISSN
1434-1948

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Bis(amidinate) Complexes of Silicon and
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The synthesis of novel bis(amidinate) silicon and germanium complexes is described. The reaction of two equiv. of [MeC(NiPr) 2 ]Li • THF (1) with SiCl 4 , GeCl 4 or GeCl 2 •dioxane affords [MeC(NiPr) 2 ] 2 SiCl 2 (2), [MeC(NiPr) 2 ] 2 GeCl 2 (3) and

First-Row Transition Metal Bis(amidinate
First-Row Transition Metal Bis(amidinate) Complexes; Planar Four-Coordination of FeII Enforced by Sterically Demanding Aryl Substituents
✍ Christian A. Nijhuis; Erica Jellema; Timo J. J. Sciarone; Auke Meetsma; Peter H. 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 198 KB

## Abstract The sterically hindered benzamidinate ligand [PhC(NAr)~2~]^–^ (Ar = 2,6‐__i__Pr~2~C~6~H~3~) has been employed to prepare bis(amidinate) complexes [{PhC(NAr)~2~}~2~M] of the divalent first‐row transition metals Cr–Ni (1–5). For Cr (planar), Mn and Co (tetrahedral) the observed structures