Reactivity of palladium(0) complexes in the oxidative addition of allylic acetates
✍ Scribed by Christian Amatore; Sophie Gamez; Anny Jutand; Gilbert Meyer; Loı̈c Mottier
- Book ID
- 108317706
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 178 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0013-4686
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📜 SIMILAR VOLUMES
The oxidative addition of the allylic acetate, CH 2 CH À CH 2 À OAc, to the palladium(0) complex [Pd 0 (P,P)], generated from the reaction of [Pd(dba) 2 ] with one equivalent of P,P (P,P dppb 1,4-bis(diphenylphosphanyl)butane, and P,P dppf 1,1'-bis(diphenylphosphanyl)ferrocene), gives a cationic (h
The reaction behavior of a transient olefin-palladium(0) complex after the first allylation was studied. Highly efficient palladium-catalyzed cascade double alkylation of a diallylic substrate is achieved by tuning the ligands. As a result, bidentate ligands which could form cyclic catalysts with a