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Oxidative Addition of Allylic Carbonates to Palladium(0) Complexes: Reversibility and Isomerization

✍ Scribed by Christian Amatore; Sophie Gamez; Anny Jutand; Gilbert Meyer; Marcial Moreno-Mañas; Lurdes Morral; Roser Pleixats

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
153 KB
Volume
6
Category
Article
ISSN
0947-6539

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Rate and Mechanism of the Reversible Formation of Cationic (η3-Allyl)- palladium Complexes in the Oxidative Addition of Allylic Acetate to Palladium(0) Complexes Ligated by Diphosphanes
✍ Christian Amatore; Sophie Gamez; Anny Jutand 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 155 KB 👁 1 views

The oxidative addition of the allylic acetate, CH 2 CH À CH 2 À OAc, to the palladium(0) complex [Pd 0 (P,P)], generated from the reaction of [Pd(dba) 2 ] with one equivalent of P,P (P,P dppb 1,4-bis(diphenylphosphanyl)butane, and P,P dppf 1,1'-bis(diphenylphosphanyl)ferrocene), gives a cationic (h