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Reactivity of nitroso oxides. Oxygen transfer as an electrophilic peroxy radical

✍ Scribed by Sawaki, Yasuhiko; Ishikawa, Shinji


Book ID
120977377
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
389 KB
Volume
109
Category
Article
ISSN
0002-7863

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The reaction of methylviologen (MV ‫ם2‬ ) with tributylphosphine (1p) and diethylphenylphosphine (1q) in the presence of an alkyl-substituted pyridine (2) was found to take place through a singleelectron transfer (SET) from 1 to MV ‫ם2‬ followed by nucleophilic attack by 2 on the resulting phosphine