๐”– Bobbio Scriptorium
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Reactivity of nitriles of fluoro- and fluoronitro-substituted garboxylic acids toward the methyl radical

โœ Scribed by V. P. Sass; A. N. Voronkov; T. A. Nadervel'; V. P. Stolyarov; S. V. Sokolov; A. V. Fokin


Book ID
112442291
Publisher
Springer
Year
1979
Tongue
English
Weight
223 KB
Volume
28
Category
Article
ISSN
1573-9171

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## Abstract The first synthesis of methoxyโ€substituted exocyclic (__E__)โ€ and (__Z__)โ€unsaturated methyl pyranosides is reported involving the __syn__ elimination of a selenoxide derivative as a key step. The rearrangement of these exocyclic enol ethers in the presence of TIBAL and DIBALโ€H is also