Abstractionof bensylic hydrogenatoms Qyatomic bromine (fromCbroam succiniaide)~ndtgrthetrichloroathyl~dical, fmmbenzyl s&b1 ether (I,B-H)andbemaldehyde dimsthylacetal (I,R-0%) has recently teen shown1 to proceed by the follwzlng nmchanism:-Ph.CHR.(Olb) + Br\* (or4C13) + Ph.k(OMs)
โฆ LIBER โฆ
Reactivity of nitriles of fluoro- and fluoronitro-substituted garboxylic acids toward the methyl radical
โ Scribed by V. P. Sass; A. N. Voronkov; T. A. Nadervel'; V. P. Stolyarov; S. V. Sokolov; A. V. Fokin
- Book ID
- 112442291
- Publisher
- Springer
- Year
- 1979
- Tongue
- English
- Weight
- 223 KB
- Volume
- 28
- Category
- Article
- ISSN
- 1573-9171
No coin nor oath required. For personal study only.
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## Abstract The first synthesis of methoxyโsubstituted exocyclic (__E__)โ and (__Z__)โunsaturated methyl pyranosides is reported involving the __syn__ elimination of a selenoxide derivative as a key step. The rearrangement of these exocyclic enol ethers in the presence of TIBAL and DIBALโH is also