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Reactivity of NCN-Chelated (NCN = C 6 H 3 -2,6-(CH 2 NMe 2 ) 2 ) Antimony(III) and Bismuth(III) Oxides toward Oxides of Arsenic

✍ Scribed by Svoboda, Tomáš; Jambor, Roman; Růžička, Aleš; Jirásko, Robert; Lyčka, Antonín; Proft, Frank De; Dostál, Libor

Book ID
120563863
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
877 KB
Volume
31
Category
Article
ISSN
0276-7333

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The 2:1 cyanocuprate [Ar 2 Cu(CN)Li 2 (THF) 4 ] `(1, Ars[C 6 H 4 CH 2 NMe 2 -2] y ) is obtained as the only product in the reaction of two equivalents of ArLi with one equivalent of CuCN in tetrahydrofuran (THF) at y788C. The X-ray crystal structure reveals an ionic polymeric chain consisting of con