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Reactivity of Metallophosphide Anions with Electrophilic (Arene)tricarbonylmetal Complexes

✍ Scribed by Virginie Comte; Jean Philippe Tranchier; Françoise Rose-Munch; Eric Rose; Danièle Perrey; Philippe Richard; Claude Moïse

Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 150 KB
Volume: 2003
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.200200531

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✦ Synopsis

Abstract

Reaction of metallophosphide anions [(CO)~x~M′PPh~2~]^−^ (M′ = Cr, Fe) with neutral tricarbonyl(η^6^‐fluoroarene)chromium and cationic (η^6^‐arene)tricarbonylmanganese complexes give rise to the formation of dinuclear complexes. These complexes are obtained either by substitution of the fluoride anion in the (arene)chromium complexes, or by addition to the ring in the (arene)manganese complexes. The X‐ray structure of one homodimetallic (Cr−Cr) complex was obtained and compared with its solution structure. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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