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ChemInform Abstract: Condensation Reactions of Planar Chiral Tricarbonyl-chromium-complexed Benzylic Alcohols and Acetates with Reactive Arenes.

✍ Scribed by Sorin I. Rosca; Raluca Stan; Cristina Ott; Elena Parlea

Publisher
John Wiley and Sons
Year
2011
Weight
26 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Condensation Reactions of Planar Chiral Tricarbonyl-chromium-complexed Benzylic Alcohols and Acetates with Reactive Arenes. -Condensation reactions of planar chiral tricarbonyl chromium complexes containing one or two reactive benzylic sites with various aryl compounds under mild reaction conditions using BF3β€’OEt2 as catalyst are presented. The reactivity of the arenes and the nature of the ortho-substituent of the planar chiral starting complex influence the product yields. -(ROSCA*,

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