Reactivity of an Aromatic σ,σ,σ-Triradical: The 2,4,6-Tridehydropyridinium Cation
✍ Scribed by Bartłomiej J. Jankiewicz; Anthony Adeuya; Michael J. Yurkovich; Nelson R. Vinueza; Samuel J. Gardner III; Meng Zhou; John J. Nash; Hilkka I. Kenttämaa
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 523 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0044-8249
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## Abstract The reactivity of 3‐hydroxy‐2,4,6‐tridehydropyridinium cation was found to be drastically different from the reactivity of 2,4,6‐tridehydropyridinium cation. While the latter triradical reacts with tetrahydrofuran, dimethyl disulfide and ally iodide via three consecutive atom or group a
## Ž The electronic structure of borabenzene C H B, known also as borinane, borinine, 5 5 . Ž . borine is studied using modern valence bond theory in its spin-coupled SC form. Three different types of SC wave functions-with six active orbitals and with four and eight active orbitals-are used to