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From 1σ4, 2σ2 to 1σ4, 2σn-Diphosphetes (n = 3–6): The Surprising Persistence of the PP bond

✍ Scribed by Muriel Sanchez; Dr. Régis Réau; Dr. Françoise Dahan; Prof. Dr. Manfred Regitz; Dr. Guy Bertrand


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
386 KB
Volume
35
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES


Von 1σ4, 2σ2- zu 1σ4, 2σn-Diphospheten (
✍ Muriel Sanchez; Dr. Régis Réau; Dr. Francoise Dahan; Dr. Manfred Regitz; Dr. Guy 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 389 KB

Ohne Zerstörung des Vierringgerüsts läßt sich die Koordinationszahl des σ^2^‐Phosphoratoms eines 1σ^4^, 2σ^2^‐Diphosphets bis auf sechs erhöhen, wie die unten abgebildete Reihe zeigt.magnified image

Cateholates as σ- and π-Donationg Ligand
✍ Prof. Dr. Donald J. Darensbourg; Dipl.-Chem. Kevin K. Klausmeyer; Dr. Brian L. M 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 260 KB

&, = 0.032); equivalent reflections were merged. The structure was solved by a combination of Patterson and difference Fourier techniques. The final cycle of full-matrix least-squares refinement was based on 5784 observed reflections ( I > 3.00a(I)) and 326 variable parameters and converged (largest