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Reactivity of alkyl and polychloroalkyl radicals toward 1-hexene

✍ Scribed by Kim, V. ;Shostenko, A. G. ;Myshkin, V. E. ;Kartashev, N. I.


Book ID
112685009
Publisher
Springer
Year
1979
Tongue
English
Weight
170 KB
Volume
11
Category
Article
ISSN
0133-1736

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Rate constants for the reactions of tert-butoxy radicals (generated by the thermal decomposition of di-tert-butylperoxyoxalate) with several sulfur containing compounds have been measured a t 310 K in benzene. Hexanethiol ( k = 6.5 x lO'M-'s-') reacts considerably faster than alkyl sulfides and disu