𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Homolytic Reactivity of Ligated Boranes toward Alkyl, Alkoxyl, and Peroxyl Radicals

✍ Scribed by Lucarini, Marco; Pedulli, Gian Franco; Valgimigli, Luca

Book ID
126848318
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
107 KB
Volume
61
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Rate constants and transition-state geom
Rate constants and transition-state geometry of reactions of alkyl, alkoxyl, and peroxyl radicals with thiols
✍ Evgeny Denisov; Crissostomos Chatgilialoglu; Aleksander Shestakov; Taisa Denisov πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 149 KB

## Abstract Enthalpy, activation energy, and rate constant of 9 alkyl, 3 acyl, 3 alkoxyl, and 9 peroxyl radicals with alkanethiols, benzenethiol, and L‐cysteine are calculated. The intersection parabolas model is used for activation energy calculations. Depending on the structure of attacking radic

Reactivity of tert-butoxy radicals towar
Reactivity of tert-butoxy radicals towards thiols, alkyl sulfides, and alkyl disulfides
✍ M. V. Encinas; E. A. Lissi; C. Majmud; A. F. Olea πŸ“‚ Article πŸ“… 1989 πŸ› John Wiley and Sons 🌐 English βš– 326 KB

Rate constants for the reactions of tert-butoxy radicals (generated by the thermal decomposition of di-tert-butylperoxyoxalate) with several sulfur containing compounds have been measured a t 310 K in benzene. Hexanethiol ( k = 6.5 x lO'M-'s-') reacts considerably faster than alkyl sulfides and disu