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Reactivity of acylsilane phenylhydrazones with phosphorus trichloride

✍ Scribed by Giuseppa Bartoli; Marcella Bosco; Renato Dalpozzo; Enrico Marcantoni


Book ID
104228504
Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
100 KB
Volume
31
Category
Article
ISSN
0040-4039

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The reaction between a" alcohol and a large excess of PC13 generally gives a dichlorophosphite, which on hydrolysis affords a phosphite. Thus, treatment of a" Ip\* ribonucleoside with PC13 should give, after hydrolysis and de-blocking the protective group, a ribonucleoside-5'-phosphite. Contrary to