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Reactive Sulfur Species: Kinetics and Mechanisms of the Oxidation of Cysteine by Hypohalous Acid to Give Cysteine Sulfenic Acid

✍ Scribed by Nagy, Péter; Ashby, Michael T.


Book ID
111688211
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
175 KB
Volume
129
Category
Article
ISSN
0002-7863

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Kinetics and mechanism of the oxidation
✍ Ivan Valent; Igor Schreiber; Miloš Marek 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 98 KB 👁 2 views

The kinetics and mechanism of the reaction between nitrous acid and bromine are studied in dilute sulfuric acid medium, using both the stopped-flow method and conventional spectrophotometry. The partial reaction order with respect to Br 2 moderately differs from 1, showing a saturation at a higher c