Reactive scattering of O(1D) + H2
โ Scribed by R.J. Buss; P. Casavecchia; T. Hirooka; S.J. Sibener; Y.T. Lee
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 594 KB
- Volume
- 82
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Rccerved 21 July f981
The angular and velocity distribution of OIi product from the O(l D) + H2 reactron at 2.7 kcal/moIc coIhsron energy has been obtained in a crossed molecular beam study. The product 1s found to be forward-backward symmetric, most of the re_ actron occurs through insertion of the oxygen to form ground electronic state II20
๐ SIMILAR VOLUMES
## Abstract The reaction of O(^1^__D__) with CH~4~ was studied to determine the efficiency of H~2~ production in a direct process, and it was found to be 0.11 ยฑ 0.02. Thus the two channels which account for all of the reaction between O(^1^__D__) and CH~4~ in the gas phase are equation image
The periodic orbit reduction method is used to analyse time-delay peaks in exact 3D quantal computations. Ofthe six observed peaks in the H + H2 reaction three are related to resonances, the other three to adiabatic barriers.
Accurate CC calculations of 3D quantum reactive scattering using hyperspherical (APH) coordinates are reported for both zero and non-zero total angular momentum J and for both symmetric (H + HZ) and unsymmetric (D + HZ) mass combinations. Accurate 3D reactive scattering calculations are now possible