Reactive scattering of methyl radicals: CH3 + ICl
β Scribed by C.F. Carter; M.R. Levy; R. Grice
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 165 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Angular distribution measurements for CH31 reactive scattering from CHs + ICl are reported. The lab. angular distribution indicates broad sideways peaking about 6 = 90" in the c.m. differential cross section. The c.m. differential cross section shifts from sideways to backward recoil for reaction of CHs with I, Br. Cl atoms of halogen molecules
π SIMILAR VOLUMES
A 6 initio molecular orbital calculations at the MP2/6-31G\*//6-31G\* + ZPVE level of theory suggest that the ion (CH,),S+--CH,' is 75 k J mol-' higher in energy than ionized ethyl methyl sulfide. However, this distonic ion is stable toward isomerization to the conventional structure: the two ions
The technique of resonance enhanced multiphoton ionization has been applied to in situ detection of methyl radicals in high-temperature atmospheric pressure CH, pyrolysis. The detection is via three-photon ionization using two-photon resonances to the 3p \*A;' state 'of CH; at 333.5 and 329.5 nm for