Reactive scattering of a supersonic methyl beam
β Scribed by S.M.A. Hoffmann; D.J. Smith; J.H. Williams; R. Grice
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 310 KB
- Volume
- 113
- Category
- Article
- ISSN
- 0009-2614
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A hΓgh pressure microwavc discharge source operating tvith a dilute mixture of 02 in He kas been uscd to produce a supcrsonic nozzle bcam of 0 atoms seeded in He. Ttiis source has been used to sfrrdy the reactive scattering of Cl atoms with c/z and CS2 malccules at an initial translatΓ¬onal energy E
Angular distribution measurements for CH31 reactive scattering from CHs + ICl are reported. The lab. angular distribution indicates broad sideways peaking about 6 = 90" in the c.m. differential cross section. The c.m. differential cross section shifts from sideways to backward recoil for reaction of
Recewed 24 November I98 I The reactive smttermg probablhty as a function of orlcntatlon of CH31 with respect to mcdcnt Rb 1s measured over .I range of scattermg angles. Whercasa large reaclwc asymmetry IS observed for cm +acksc3ttcred Rbl (stcrrc factorf= 0 44). forward (c.m.) scattermg IS much less