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Reactive scattering of H and D atoms. II. isotope effect on the angular distribution of H, D + NO2

✍ Scribed by Hellmut Haberland; Peter Rohwer; Konrad Schmidt


Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
593 KB
Volume
5
Category
Article
ISSN
0301-0104

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The lack of leaving-atom isotope effects
✍ W.H. Breckenridge; Jiang-Hua Wang πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 English βš– 587 KB

Simple "half-collision" classical trajectories on model potential surfaces show that the lack of leaving-atom isotope effects on initial rotational state distributions P(N) in reactions of the type M\*+H2 (HD) -+MH( v, N) +H (D) would result from decomposition of H-M-H( D) intermediates on anisotrop