๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Reactive enolates from enol silyl ethers

โœ Scribed by Kuwajima, Isao; Nakamura, Eiichi


Book ID
120938111
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
838 KB
Volume
18
Category
Article
ISSN
0001-4842

No coin nor oath required. For personal study only.


๐Ÿ“œ SIMILAR VOLUMES


Silyl Enol Ethers
โœ S. Kobayashi; K. Manabe; H. Ishitani; J.-I. Matsuo ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› John Wiley and Sons โš– 48 KB ๐Ÿ‘ 1 views
A facile generation of enolates from sil
โœ Wensheng Yu; Zhendong Jin ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 101 KB

Cyclic silyl enol ethers were successfully cleaved by EtOK to generate the corresponding enolates. Reactions with EtOK were faster and the corresponding enolates could be trapped by electrophiles and oxidants to give the kinetic products exclusively.

Allylation and benzylation of enolates d
โœ Sylvain Ponthieux; Francis Outurquin; Claude Paulmier ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 616 KB

ct-PheJwIxelanyl Y-unsaturated ketones uere obtained lhrouL, h al@laliolt (!/' enolale.~ generated hy potassium I-buloxide cleavage (!/' fi-phel~vlselan.vl si@l emd ether.Y derived

Phenylthiomethylstannylation of silyl en
โœ Javed Iqbal ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 212 KB

Silyl enol ethers (2) react with trihutyl [(phenylthio) chloromethyl] stannane (1) in the presence of Zinc bromide to give B-phenylthiomethylstannyl ketones (3) in good yields. Silyl dienol ethers (4) mainly give products (5) due to y-attack, under these conditions. S-Stannyl Carbonyl compounds have