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A facile generation of enolates from silyl enol ethers by potassium ethoxide

โœ Scribed by Wensheng Yu; Zhendong Jin


Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
101 KB
Volume
42
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Cyclic silyl enol ethers were successfully cleaved by EtOK to generate the corresponding enolates. Reactions with EtOK were faster and the corresponding enolates could be trapped by electrophiles and oxidants to give the kinetic products exclusively.


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