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Reactions with thioethoxide ion in dimethylformamide. I. Selective demethylation of aryl methyl ethers

✍ Scribed by Feutrill, GI; Mirrington, RN

Book ID: 120971217
Publisher: Commonwealth Scientific and Industrial Research Organisation Publishing
Year: 1972
Tongue: English
Weight: 561 KB
Volume: 25
Category: Article
ISSN: 0004-9425
DOI: 10.1071/CH9721719

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## Abstract The reactivity of the lithium halides in 83.3% pyridine‐dimethylformamide changes from Cl^−^ > Br^−^ > I^−^ to Br^−^ > I^−^ to Br^−^ > I^−^ > Cl^−^ with increasing concentration of the salt from 0 to 0.35 M. This behaviour is explained by ion pairing which reduces the concentration of r