Reaction of non-activated olefines with active methylene compounds was accomplished under solid-liquid phase-transfer conditions, in the presence of iodine, to give electrophilic cyclopropanes of a wide range of substituents. Several data to the mechanism of the reaction are also given.
✦ LIBER ✦
Reactions ofO,O-dialkyldithiophosphoric acids with non-activated α-olefins
✍ Scribed by I. S. Nizamov; I. D. Nizamov; Ya. E. Popovich; R. A. Cherkasov
- Book ID
- 114993534
- Publisher
- Springer
- Year
- 2012
- Tongue
- English
- Weight
- 215 KB
- Volume
- 82
- Category
- Article
- ISSN
- 1070-3632
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Thermal reaction of butyl N-(p-toluenesulphonyl)iminoacetate and diethyl mesoxalate with ketones leads to the derivatives of f-0x0-d-amino-acids and c-oxo-o(-hydroxy--acids, respectively. 1 b.p's or m.p's and ZR spectra are collected in Table 1 and H NMR data in Table 2. All new compounds gave corre