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REACTIONS OF β-NITROSTYRENES WITH STABILIZED NUCLEOPHILES

✍ Scribed by Ching-Fa Yao; Cherng-Shi Yang; Hui-Yu Fang

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
245 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

&Nitrostyrsnes1 reactwithstabilizednucleophilesto generatehydroximoyl chloride2 after workupwith ice coldconcentratedhydrnctdoricacid. One-potsynthesisof tive-membsredcarbocyclesor cyclic ethers from the Michasl additionof the carbonnucleophilesor atkoxidesto the &nitrostyrenesis repted. O 1997Elsevier ScienceLtd.

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One-pot synthesis of the hydroximoyl chl
One-pot synthesis of the hydroximoyl chlorides and [3.3.0] bicyclic compounds from the reactions of β-nitrostyrenes with stabilized nucleophiles
✍ Kuo-Hsi Kao; Cherng-Shi Yang; Ju-Tsung Liu; Wen-Wei Lin; Hui-Yu Fang; Ching-Fa Y 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 960 KB

fl-Nitrostyrenes 1 react with various stabilized nucleophiles to generate hydtoximoyl chlorides and nit~-~alkargS after workup with ice cold concentrated hydtochlccic acid. One-pot synthesis of bicyclic woducts from the Michael addition of dLffetent nucleophfles with fl-nitrostyrenes l is ~.