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One-pot synthesis of the hydroximoyl chlorides and [3.3.0] bicyclic compounds from the reactions of β-nitrostyrenes with stabilized nucleophiles

✍ Scribed by Kuo-Hsi Kao; Cherng-Shi Yang; Ju-Tsung Liu; Wen-Wei Lin; Hui-Yu Fang; Ching-Fa Yao; Kwunmin Chen

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
960 KB
Volume
54
Category
Article
ISSN
0040-4020

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✦ Synopsis

fl-Nitrostyrenes 1 react with various stabilized nucleophiles to generate hydtoximoyl chlorides and nit~-~alkargS after workup with ice cold concentrated hydtochlccic acid. One-pot synthesis of bicyclic woducts from the Michael addition of dLffetent nucleophfles with fl-nitrostyrenes l is ~.

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