𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Reactions of α-olefins with soluble complex catalysts of the ziegler type and the mechanism of initiation of the polymerization of ethylene

✍ Scribed by A.Ye. Shilov; A.K. Shilova; B.N. Bobkov

Book ID
118356030
Publisher
Elsevier Science
Year
1963
Weight
608 KB
Volume
4
Category
Article
ISSN
0032-3950

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Competing side reactions in the polymeri
Competing side reactions in the polymerization of α-olefins by ziegler-natta catalysts
✍ Ketley, A. D. ;Moyer, J. D. 📂 Article 📅 1963 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 490 KB

## Abstract The polymerization of 3‐methylbutene‐1 by TiCl~3~–Al(C~2~H~5~)~3~ catalysts in dilute solution above 80°C. yields a polymer which is contaminated with polyethylene. By using tagged aluminum alkyl, this polyethylene was shown to arise almost wholly by displacement of ethylene from the al

Ethylene polymerization reactions with Z
Ethylene polymerization reactions with Ziegler–Natta catalysts. II. Ethylene polymerization reactions in the presence of deuterium
✍ Y. V. Kissin; A. J. Brandolini 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 151 KB 👁 1 views

Ethylene polymerization reactions with many Ziegler-Natta catalysts exhibit several features which differentiate them from polymerization reactions of ␣-olefins: a relatively low ethylene reactivity, higher polymerization rates in the presence of ␣-olefins, a high reaction order with respect to ethy