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Reactions of Zirconocene−Alkyne Complexes with Polar Functionalized Olefins †

✍ Scribed by Sun, Hongsui; Burlakov, Vladimir V.; Spannenberg, Anke; Baumann, Wolfgang; Arndt, Perdita; Rosenthal, Uwe

Book ID
127327908
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
104 KB
Volume
21
Category
Article
ISSN
0276-7333

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Isomerization of olefins by titanocene a
Isomerization of olefins by titanocene and zirconocene alkyne complexes
✍ A. Ohff; V.V. Burlakov; U. Rosenthal 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 690 KB

An efficient isomerization of aliphatic and cyclic olelins is achieved by using well-defined metallocene alkyne complexes as catalysts. Titanocene complexes isomerize I-alkenes to internal alkenes under mild conditions. The titanium complex was recovered quantitatively. Cyclic olcfins, e.g. cyclohex