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Reactions of tris[bis(trimethylsilyl)amino]aluminum with ammonia and pyrolysis studies

โœ Scribed by Paciorek, K. J. L.; Nakahara, J. H.; Hoferkamp, L. A.; George, C.; Flippen-Anderson, J. L.; Gilardi, R.; Schmidt, Wayde R.


Book ID
126880883
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
860 KB
Volume
3
Category
Article
ISSN
0897-4756

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The Reaction of Transient 1,1-Bis(trimet
โœ Katrin Sternberg; Helmut Reinke; Hartmut Oehme ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 170 KB ๐Ÿ‘ 2 views

Tris(trimethylsilyl)silyllithium (3) reacted with aldehydes and ketones (molar ratio 2 : 1) according to a modified Peterson mechanism under formation of transient silenes, which were immediately trapped by excess 3 to give the organolithium derivatives (Me 3 Si) 3 SiSi(SiMe 3 ) 2 C(Li) ล”1 R 2 (7).