Reactions of triplet carbenes with sulfides and disulfides: ylide vs. radical formation
โ Scribed by Alberti, A.; Griller, D.; Nazran, A. S.; Pedulli, G. F.
- Book ID
- 127238126
- Publisher
- American Chemical Society
- Year
- 1986
- Tongue
- English
- Weight
- 640 KB
- Volume
- 108
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
The gas-phase ionhnolecule reactions of the CH,SCDCN, CH,SCCN and 'CH,SCDCN ions formed in the reaction of the 0-' ion with CH,SCD,CN have been studied with the use of Fourier-transform ion cyclotron resonance (FTICR). In the reaction of the CH,SCDCN carbanion with the model substrate, dimethyl disu
B-Ketoalkylsulfonium salts are ordinarily made by reaction of an o-halogenoketone with an organic sulfide. Phenacyl bromide is often used (eq. 1); a-bromoesters (=.a., methyl bromoacetate) are also used. 2 This method is quite old, having been used, for example, by Clarke