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Electron paramagnetic resonance of tert-butoxy radical reactions with sulfides and disulfides

✍ Scribed by Adams, John Quincey.


Book ID
126093250
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
334 KB
Volume
92
Category
Article
ISSN
0002-7863

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Rate constants for the reactions of tert-butoxy radicals (generated by the thermal decomposition of di-tert-butylperoxyoxalate) with several sulfur containing compounds have been measured a t 310 K in benzene. Hexanethiol ( k = 6.5 x lO'M-'s-') reacts considerably faster than alkyl sulfides and disu

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## Abstract The copolymerization of __p__‐__tert__‐butoxystyrene (1) (M~1~) and dibutyl fumarate (2) (M~2~) initiated with dimethyl 2,2′‐azobisisobutyrate (3) was studied in benzene at 60Β°C kinetically and by means of electron paramagnetic resonance (EPR) spectroscopy. The monomer reactivity ratios