Electron paramagnetic resonance of tert-butoxy radical reactions with sulfides and disulfides
β Scribed by Adams, John Quincey.
- Book ID
- 126093250
- Publisher
- American Chemical Society
- Year
- 1970
- Tongue
- English
- Weight
- 334 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Rate constants for the reactions of tert-butoxy radicals (generated by the thermal decomposition of di-tert-butylperoxyoxalate) with several sulfur containing compounds have been measured a t 310 K in benzene. Hexanethiol ( k = 6.5 x lO'M-'s-') reacts considerably faster than alkyl sulfides and disu
## Abstract The copolymerization of __p__β__tert__βbutoxystyrene (1) (M~1~) and dibutyl fumarate (2) (M~2~) initiated with dimethyl 2,2β²βazobisisobutyrate (3) was studied in benzene at 60Β°C kinetically and by means of electron paramagnetic resonance (EPR) spectroscopy. The monomer reactivity ratios