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Reactions of trifluoromethyl-substituted arylacetylenes with arenes in superacids

✍ Scribed by Alkhafaji, H. M. H.; Ryabukhin, D. S.; Muzalevskiy, V. M.; Osetrova, L. V.; Vasilyev, A. V.; Nenajdenko, V. G.


Book ID
120516801
Publisher
SP MAIK Nauka/Interperiodica
Year
2013
Tongue
English
Weight
334 KB
Volume
49
Category
Article
ISSN
1070-4280

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Regioselective electrophilic trifluorome
✍ SΓ©bastien Debarge; Bruno Violeau; Nohair Bendaoud; Marie-Paule Jouannetaud; Jean πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 223 KB

In a one pot procedure, treatment of chloro or methyl substituted acetanilides in HF/SbF 5 /CCl 4 followed by addition of HF/pyridine yields trifluoromethyl derivatives with high regioselectivity.