Reactions of trifluoroamine oxide: a route to acyclic and cyclic fluoroamines and N-nitrosoamines
β Scribed by Gupta, Om Dutt; Kirchmeier, Robert L.; Shreeve, Jean'ne M.
- Book ID
- 126008965
- Publisher
- American Chemical Society
- Year
- 1990
- Tongue
- English
- Weight
- 594 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
A straightforward route to polyols, amino polyols, polysubstituted lactols and lactones from readily available arenes has been devised. It uses a three-or four-step sequence involving a Birch reduction of the arene, followed by desymmetrization through dihydroxylation or aminohydroxylation and, last
Cerium-mediated conjugate additions of (diethoxyphosphinoyl)difluoromethyllithium to cyclic vinyl sulfones proceeded smoothly; reduction afforded the products of formal alkylation, attaching the difluoromethylene phosphonate group to a secondary carbon atom. With acyclic vinyl sulfones, the addition