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Reactions of transition metal compounds with macrocyclic alkadiynes : IV*. Intramolecular transannular cyclizations with cyclopentadienyldicarbonylrhodium

✍ Scribed by R.B. King; M.N. Ackermann


Book ID
108351255
Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
836 KB
Volume
67
Category
Article
ISSN
0022-328X

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## Abstract The anion radical of acetylacetonate is formed by the reaction of nickel (II) acetylacetonate with Grignard reagents. From the two coupling constants found in the e.s.r. spectrum, the one of 2Β·6 G was assigned to the methine proton and the one of 12Β·5 G to the six equivalent methyl prot