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Photoinduced reactions of organic compounds with transition metal complexes. Communication 1. First example of substitution in the aromatic nucleus in photoexcitation of an electrophilic reagent: formation of σ-aryl complexes of Pt(IV) in the reaction of PtCl62−2with arenes

✍ Scribed by G. B. Shul'pin; G. V. Nizova; A. E. Shilov; A. T. Nikitaev; M. V. Serdobov

Book ID
112448438
Publisher
Springer
Year
1984
Tongue
English
Weight
492 KB
Volume
33
Category
Article
ISSN
1573-9171

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Photoinduced reactions of organic compou
Photoinduced reactions of organic compounds with transition metal complexes: III. Formation of a σ-methyl complex of platinum(IV) and a π-ethylene complex of platinum(II) in photochemical and thermal reactions of PtCl62− with methyl and ethyl derivatives of tin or germanium. thermal oxidative addition of Me4Sn to PtCl42− to afford the σ-methyl complex of platinum(IV)
✍ G.B. Shul'pin; G.V. Nizova; A.N. Kitaigorodskii; M.V. Serdobov 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 542 KB