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Reactions of transition-metal carbonyl anions with dioxygen in the gas phase

✍ Scribed by Lane, Kelley; Sallans, Larry; Squires, Robert R.


Book ID
126165579
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
407 KB
Volume
106
Category
Article
ISSN
0002-7863

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## Abstract The reactions of metal carbonyl anions (M(CO)~__n__~^βˆ’^; M = Cr, Mn and Fe; __n__ = 1–3) with __n__‐heptane, water and methanol were studied with use of a Fourier transform ion cyclotron resonance (FT‐ICR) mass spectrometer equipped with an external ion source. The M(CO)~__n__~^βˆ’^ ions