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Reactions of the ‘ferrole’ complex [Fe2(CO)6(C2Et2)2] with group 15 donor ligands and with alkynes. Stepwise formation and disengagement of tropones. Crystal and molecular structure of [Fe2(CO)5{(CEt)2 CO(CEt)2 CHCPh}]

✍ Scribed by Roberto Giordano; Enrico Sappa; Daniele Cauzzi; Giovanni Predieri; Antonio Tiripicchio


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
902 KB
Volume
511
Category
Article
ISSN
0022-328X

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Cleavage of the Fe–Fe Bond of (Me2SiSiMe
✍ Hud-Lin Sun; Zhen-Sheng Zhang; Xiu-Zhong Zhou 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 327 KB 👁 1 views

## Abstract The reaction of the title cyclic complex (1) with sodium amalgam in THF resulted in the expected cleavage of the Fe—Fe bond to afford bis‐sodium salt (Me~2~SiSiMe~2~) [η^5^‐C~5~H~4~Fe (CO)~2~Na]~2~ (4). The latter was not isolated and was used directly to react with MeI, PhCH~2~Cl, CH~3