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Reactions of the Ethyl Radical. II. Addition to Unsaturated Hydrocarbons

โœ Scribed by James, D. G. L.; Steacie, E. W. R.


Book ID
120144828
Publisher
The Royal Society
Year
1958
Tongue
English
Weight
801 KB
Volume
244
Category
Article
ISSN
0962-8444

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By catalysis of AIBN, tosyl cyanide adds in a regio-and stereoselective manner to unsaturated hydrocarbons, including alkenes, dienes and 1-hexyne. Accompanied intramolecular cyclization and ring cleavage were effected in reactions with norbornadiene, 1,5-cyclooctadiene and pinenes. Toluenesulfonyl