The reaction between BH4and CH20 has been investigated in the gas phase using ion cyclotron resonance spectroscopy. MO hydride transfer from
Reactions of the Borohydride Group with the Proton Donors Hydroxylammonium, Methoxyammonium, and Hydraziniummagnesium Ions
โ Scribed by Gunderloy, Frank C.
- Book ID
- 126311385
- Publisher
- American Chemical Society
- Year
- 1963
- Tongue
- English
- Weight
- 298 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0020-1669
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๐ SIMILAR VOLUMES
0-Deprotonation of 3 is, ofcourse, possible too. It is even more dominant than N-deprotonation for obvious reasons. It can be neglected, however, in this context, because 0 -deprotonation is a side-equilibrium which does not lead to the reaction product NzO.
The prolon affinities of SK0 and H&Se were delermined by pulsed ICR techniques and found IO be 157&3 and 186k 1 kcal/mol. respectively. The proron aflinity of Hz% and of H&S were found lo be 171.2\*0.2 and l&X7\* 1.0 kcal/mol. ## respectively. in ogreemenr with earlier determinations. The gas-pha