𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Reactions of some nitrosoperfluoroalkanes with trimethylsilyl phosphites

✍ Scribed by Heike Hund; Gerd-Volker Röschenthaler

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
242 KB
Volume
7
Category
Article
ISSN
1042-7163

No coin nor oath required. For personal study only.

✦ Synopsis

Nitrosotrifluoromethane or nitrosopentafluoroethane reacted with trimethylsilyl diethyl or tvis(trimethylsily1) phosphite to give phosphato-fluorocarbiminoor phosphato-trifluoroacetimino-phos- phonates and fluorotrimethylsilane. Some intermediate compounds could be detected by N M R spectroscopy, namely, diethyl (N-trimethylsiloxy-N-trifluoromethyl)-or diethyl (N-trimethylsiloxy-N-penta-fluoroethy1)amidophosphate and difluorocarbimino diethyl phosphate.

📜 SIMILAR VOLUMES

Reactions of fluorinated hydroxy and epo
Reactions of fluorinated hydroxy and epoxy ketones with tris(trimethylsilyl) phosphite
✍ Vitalij G. Ratner; Enno Lork; Kazimir I. Pashkevich; Gerd-Volker Röschenthaler 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 172 KB 👁 2 views

## Reacting the fluoroalkyl b-trimethylsi- R‫ס‬ Me) with tris(trimethylsilyl) phosphite gave a diastereomeric mixture of ␣,c-hydroxy phosphonic acids and their derivatives. With a fluorinated b-epoxy ketone and tris(trimethylsilyl) phosphite, corresponding silyl esters and, after hydrolysis, an ␣-

Reaction of Trifluoromethylated β-Alkoxy
Reaction of Trifluoromethylated β-Alkoxyenones with Tris(trimethylsilyl) Phosphite: A Temperature Influence on Regioselectivity.
✍ Dmitri L. Chizhov; Gerd-Volker Roeschenthaler 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 26 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Reactions of N-phthalylamino acid chlori
Reactions of N-phthalylamino acid chlorides with trialkyl phosphites
✍ Zyta Ziora; Alina Maly; Barbara Lejczak; Pawel Kafarski; Jolanta Holband; Grażyn 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 218 KB 👁 2 views

Reaction of commercially available trialkyl phosphites with N-phthalylamino acids gave mixtures of seven products, whereas the same reaction carried out with pure triethyl phosphite yielded only the desired 2-(N-phthalylamino)-1-oxoalkanephosphonates. These compounds underwent rearrangement to the s