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Reactions of silver perchlorate and of silver triflate with alkyl iodides. Solvent inhibition of isomerization

โœ Scribed by Beard, Charles D.; Baum, Kurt


Book ID
121277722
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
475 KB
Volume
39
Category
Article
ISSN
0022-3263

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Metal atom reactions with fluorocarbons
โœ Kenneth J. Klabunde ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 314 KB

Codeposition of silver vapor with E-alkyl iodides at -196'C followed by matrix warmup yields AgI and RfAg. These reactions serve as the first examples of formation of R-M compounds employing the metal atom technique, and of formation of primary RfAg compounds. Matrix dilution experiments indicate, c