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Metal atom reactions with fluorocarbons viii. Silver vapor with f-alkyl iodides with formation of f-alkylsilver compounds

โœ Scribed by Kenneth J. Klabunde

Book ID
104150700
Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
314 KB
Volume
7
Category
Article
ISSN
0022-1139

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โœฆ Synopsis

Codeposition of silver vapor with E-alkyl iodides at -196'C followed by matrix warmup yields AgI and RfAg. These reactions serve as the first examples of formation of R-M compounds employing the metal atom technique, and of formation of primary RfAg compounds. Matrix dilution experiments indicate, contrary to expected results, that high RfI/Ag ratios favor RfAg formation.

๐Ÿ“œ SIMILAR VOLUMES

On the mechanism of alkyl dimer formatio
On the mechanism of alkyl dimer formation in reactions of alkyl iodides with sodium naphthalene. Evidence from reactions of 1,4-diiodobutane.
โœ John F. Garst; John T. Barbas ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 236 KB

Recent studies indicate that the initial reactions of alkyl halides with sodium naphthalene in IME are best regarded as dissociative electron-transfer reactions, with no significant competition from nucleophilic displacement reactions (Eq. 1) (1,Za). The initially-formed m + :Naph:,Na+ -R\*