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On the mechanism of alkyl dimer formation in reactions of alkyl iodides with sodium naphthalene. Evidence from reactions of 1,4-diiodobutane.

✍ Scribed by John F. Garst; John T. Barbas

Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
236 KB
Volume
10
Category
Article
ISSN
0040-4039

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✦ Synopsis

Recent studies indicate that the initial reactions of alkyl halides with sodium naphthalene in IME are best regarded as dissociative electron-transfer reactions, with no significant competition from nucleophilic displacement reactions (Eq. 1) (1,Za). The initially-formed m + :Naph:,Na+ -R*

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