Evaporation of silicon and consecutive cocondensation of the isolation of three new C 2 H 4 Si isomers [apart from the known silacyclopropene (7) and silylacetylene (8)], namely generated atoms with acetylene or ethylene in an argon matrix turnes out to be a new access to C 2 H 2 Si and C 2 H 4 Si s
Reactions of Silicon Atoms with Cyanogen: Generation and Matrix-Spectroscopic Identification of Five C2N2Si Isomers
✍ Scribed by Günther Maier; Hans Peter Reisenauer
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 119 KB
- Volume
- 2005
- Category
- Article
- ISSN
- 1434-193X
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📜 SIMILAR VOLUMES
Cocondensation of thermally generated silicon atoms with chemical behavior of these species are described. Structural assignments are made by the comparison of experimental hydrogen cyanide in an argon matrix can be used as an access to compounds of the composition CHNSi and CNSi. with calculated I
Pulsed flash pyrolysis in combination with matrix isolation of isotopomer. Upon irradiation of matrix-isolated silylsilacyclopropenylidene (1) a second C 2 H 4 Si 2 isomer, namely three precursor molecules (10,11,12) led to the formation of silylsilacyclopropenylidene (1), which was identified by (s
Flash pyrolysis of 1,1-diethynyl-2,2,2-trimethyldisilane ( ) butadiynylsilylene ( ). The identification of these reactive intermediates is based on the comparison between the and triethynylsilane (18) led to the formation of two silylenes of the elemental composition C 4 H 2 Si, namely dieth-experim