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Reaction of Silicon Atoms with Hydrogen Cyanide: Generation and Matrix-Spectroscopic Identification of CHNSi and CNSi Isomers

✍ Scribed by Günther Maier; Hans Peter Reisenauer; Heiko Egenolf; Jörg Glatthaar

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
259 KB
Volume
1998
Category
Article
ISSN
1434-193X

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✦ Synopsis

Cocondensation of thermally generated silicon atoms with chemical behavior of these species are described. Structural assignments are made by the comparison of experimental hydrogen cyanide in an argon matrix can be used as an access to compounds of the composition CHNSi and CNSi.

with calculated IR spectra. Isolation, matrix-spectroscopic identification and photo-

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✍ Günther Maier; Hans Peter Reisenauer; Heiko Egenolf 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 299 KB 👁 1 views

Evaporation of silicon and consecutive cocondensation of the isolation of three new C 2 H 4 Si isomers [apart from the known silacyclopropene (7) and silylacetylene (8)], namely generated atoms with acetylene or ethylene in an argon matrix turnes out to be a new access to C 2 H 2 Si and C 2 H 4 Si s