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Reactions of ruthenium cyclopropenyl complexes with trimethylsilyl azide

✍ Scribed by Chang, Ku-Hsien; Lin, Ying-Chih

Book ID: 119993907
Publisher: Royal Society of Chemistry
Year: 1998
Tongue: English
Weight: 62 KB
Volume: 14
Category: Article
ISSN: 1359-7345
DOI: 10.1039/a802199f

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## Abstract Reactions of the ruthenium azide complex **1** with alkyl isothiocyanates give novel ruthenium thiotetraazapentalenedithione complexes **3a**−**c** containing a hypervalent sulfur atom. The ligand, bound through one sulfur atom, is derived from three isothiocyanate molecules and one nit