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Novel Thiotetraazapentalene Complexes from the Reaction of a Ruthenium Azide Complex with Alkyl Isothiocyanates

✍ Scribed by Sheng-Chin Hsu; Ying-Chih Lin; Shou-Ling Huang; Yi-Hung Liu; Yu Wang; Hwang Liu

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
115 KB
Volume
2004
Category
Article
ISSN
1434-1948

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✦ Synopsis

Abstract

Reactions of the ruthenium azide complex 1 with alkyl isothiocyanates give novel ruthenium thiotetraazapentalenedithione complexes 3aβˆ’c containing a hypervalent sulfur atom. The ligand, bound through one sulfur atom, is derived from three isothiocyanate molecules and one nitrogen atom from an azide ion. The synthesis and structural determination of 3aβˆ’c, as well as a possible mechanism for their formation is described. (Β© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

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## Abstract Kinetic and thermodynamic investigations were performed for a mixed aqueous‐organic, 1:1 (v/v) water–1,4‐dioxane medium, which was found to be an efficient solvent for the interaction of a neutral dichlorotris(triphenylphosphine) ruthenium(II), RuCl~2~(PPh~3~)~3~ complex with carbon mon