## Abstract Both amido‐(cyclopentadienyl)boranes and bis(cyclopentadienyl)boranes of the types R~2~NB(C~__x__~H~__y__~) (NR′) and R~2~NB(C~__x__~H~__y__~)~2~ (R = alkyl, trimethylsilyl; R′ = Ph; C~__x__~H~__y__~ = C~5~H~5~ (cyclopentadienyl), C~9~H~7~ (indenyl), C~13~H~9~ (fluorenyl)) were recently
✦ LIBER ✦
Reactions of pyridine-functionalized lithium alkyls with nickelocenes and nickel(II) chloride: respective formation of cyclopentadienyl-nickelalkyls and coupled organic products. X-Ray crystal structures of [(η5-C5H5)Ni{C(SiMe3)2C5H5N-2}] and {CH(SiMe 3)C5H4N-2}2
✍ Scribed by Wing-Por Leung; Hung-Kay Lee; Zhong-Yuan Zhou; Thomas C.W. Mak
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 607 KB
- Volume
- 462
- Category
- Article
- ISSN
- 0022-328X
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## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3