Reactions of primary and secondary alkoxy radicals derived from hypochlorites
β Scribed by Walling, Cheves; Clark, Roger T.
- Book ID
- 126428950
- Publisher
- American Chemical Society
- Year
- 1974
- Tongue
- English
- Weight
- 583 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The reaction pathways of n-butoxy and s-butoxy radicals have been investigated by TLC and HPLC analysis of end products, particularly peroxides and carbonyl compounds. The butoxy radicals were produced by the pyrolysis of very low concentrations of the corresponding dibutylperoxide in an atmosphere
## Abstract The nature of interaction of Co(III) complexes such as Co(III)EDTA and Co(III)NTA with transient adducts of thymine such as TOH^Λ^, T^Λβ^, and TH^Λ^ formed in the gamma radiolysis of thymine were studied. The study shows that TOH radicals do not undergo electron transfer reaction with C